MCKENNEY, MEGAN L (2022) Activation of Primary Alcohols via Metal Ligand Cooperation in (PhI2P2-)AlH and the Synthesis and Characterization of Redox Active Ligand Complex [(cat)2Si(catH)][Et3N. Doctoral thesis, UIN SAIZU Purwokeerto.
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Abstract
The oxidative addition of primary alcohols (phenol, tert-butyl alcohol, benzyl alcohol, methanol, 1-octanol) via (PhI2P2-)AlH (PhI2P = bis(imino)pyridine) was investigated for production of the corresponding aldehyde with elimination of H2. The primary alcohols utilized with β-hydrogen available (benzyl alcohol, methanol, and 1-octanol) were also investigated for catalytic turnover of H2 and the simultaneous production of its respective aldehyde. Phenol and tert-butyl alcohol reacted with the (PhI2P2-)AlH complex to afford (PhI2P-)AlH(OC6H5) and (PhI2P-)AlH(OC4H9), respectively. The reaction of (PhI2P2-)AlH with benzyl alcohol successfully afforded H2 and benzaldehyde in the presence of excess benzyl alcohol, however no evidence for the reaction was obtained.
| Item Type: | Thesis (Doctoral) |
|---|---|
| Subjects: | 500 Natural sciences and mathematics > 501 Philosophy and theory |
| Divisions: | Perpustakaan |
| Depositing User: | sdr prakerin 22 |
| Date Deposited: | 20 May 2022 02:09 |
| Last Modified: | 20 May 2022 02:09 |
| URI: | http://repository.uinsaizu.ac.id/id/eprint/13515 |
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